Q: My opponent has an
Imposing Sovereign, and my devotion to blue is 4. If I cast
Thassa, God of the Sea, does she enter tapped?
A: Nope! This seems to confuse a lot of folks, so we'll go step by step through it.
In any zone other than the battlefield, Thassa is always a creature. So on the stack (which is the zone she'll enter the battlefield from), Thassa is a creature spell. But she's a weird sort of creature spell: she has an ability that can cause her, once on the battlefield, not to be a creature. And that's where things get tricky.
Imposing Sovereign's ability creates a replacement effect, which modifies how certain permanents (creature permanents) enter the battlefield. Replacement effects, as you'll recall if you read CI regularly, apply before the event they're replacing happens. So if Imposing Sovereign's effect is going to apply, it will apply before Thassa is on the battlefield.
This means that, before Thassa enters, we need to figure out whether she's going to be a creature for Imposing Sovereign to apply to. The rules tell us (specifically, rule 614.12 tells us) what types of abilities and effects to consider when we're figuring that out, and that's a pretty short list, but it does let us look at Thassa's own ability. But at the time we're asking what her ability would do, your devotion to blue is only 4 — it won't hit 5 until after she's on the battlefield, and we're doing this before she enters.
Which means her ability answers back "devotion to blue is only 4, I wouldn't be a creature in this situation", and Imposing Sovereign's effect doesn't apply. So Thassa enters the battlefield untapped, and then as soon as she's on the battlefield your devotion is 5 and immediately she's a (still untapped) creature.